Atomic Structure

Constituents of the Atom

An atom consists of a small, dense, positively charged nucleus containing protons and neutrons, surrounded by orbiting electrons.

ParticleRelative chargeRelative massActual mass (kg)
Proton+111.67 × 10−27
Neutron011.67 × 10−27
Electron−11/18369.11 × 10−31

Specific Charge

The specific charge of a particle is its charge divided by its mass. It is measured in C kg−1.

Specific charge = Qm

Worked Example

Calculate the specific charge of a proton.

Charge = 1.60 × 10−19 C

Mass = 1.67 × 10−27 kg

Specific charge = 1.60 × 10−19 / 1.67 × 10−27 = 9.58 × 107 C kg−1

Notation and Isotopes

Nuclide notation: AZX, where A = mass number (protons + neutrons), Z = atomic (proton) number.

Isotopes are atoms with the same number of protons but different numbers of neutrons. They have the same chemical properties but different physical properties (e.g., different mass, some may be radioactive).

Key Facts

  • The strong nuclear force holds the nucleus together against electrostatic repulsion
  • Unstable nuclei can decay by alpha, beta, or gamma emission
  • The specific charge of an electron is about 1840 times that of a proton

Particles & Antiparticles

Antimatter

Every particle has a corresponding antiparticle with the same mass but opposite charge (and opposite quantum numbers).

ParticleSymbolAntiparticleSymbol
ElectronePositrone+
ProtonpAntiproton
NeutronnAntineutron
NeutrinoνeAntineutrinoν̄e

Pair Production and Annihilation

Pair production: A photon with sufficient energy creates a particle-antiparticle pair. The minimum photon energy required is 2m0c2 (twice the rest energy of the particle).

Annihilation: A particle meets its antiparticle and they are destroyed, producing two photons travelling in opposite directions (to conserve momentum).

Minimum photon energy for pair production: E = 2m0c2

Annihilation: e + e+ → 2γ

The Photon Model

Electromagnetic radiation is emitted in discrete packets of energy called photons.

E = hf = hcλ

Where h = 6.63 × 10−34 J s (Planck's constant), f = frequency, λ = wavelength, c = 3.00 × 108 m s−1.

Exam Tip

In annihilation, two photons are produced (not one) to conserve momentum. Each photon has energy equal to the rest energy of one of the particles (minimum).

Quarks & Leptons

Particle Classification

Particles are classified into two main groups based on whether they feel the strong nuclear force.

Particles Hadrons (feel strong force) Leptons (do not feel strong force) Baryons (3 quarks) Mesons (quark-antiquark) Proton (uud) Neutron (udd) Pion (π) Kaon (K) Charged e, μ, τ Neutrinos νe, νμ, ντ All hadrons are made of quarks Leptons are fundamental (not made of quarks)

Quarks

Quarks are fundamental particles that make up hadrons. There are six flavours, but at A-level you need to know three: up (u), down (d), and strange (s).

QuarkSymbolChargeBaryon numberStrangeness
Upu+2/3+1/30
Downd−1/3+1/30
Stranges−1/3+1/3−1

Antiquarks have opposite charge, baryon number, and strangeness.

Quark Composition of Hadrons

ParticleQuark compositionChargeBaryon number
Protonuud+2/3 +2/3 −1/3 = +1+1
Neutronudd+2/3 −1/3 −1/3 = 0+1
π+ud̄+2/3 +1/3 = +10
πūd−2/3 −1/3 = −10
K+us̄+2/3 +1/3 = +10

Leptons

Leptons are fundamental particles that do not feel the strong nuclear force. They include electrons, muons, taus, and their associated neutrinos.

Each lepton generation has its own lepton number: electron lepton number (Le), muon lepton number (Lμ), tau lepton number (Lτ).

Key Facts

  • Baryons = 3 quarks, Antibaryons = 3 antiquarks, Mesons = quark + antiquark
  • Quarks never exist in isolation (confinement)
  • The proton is the only stable baryon; free neutrons decay with a half-life of about 10 minutes

Particle Interactions

Conservation Laws

In all particle interactions, the following quantities must be conserved:

QuantityAlways conserved?Notes
Charge (Q)AlwaysMust balance on both sides
Baryon number (B)AlwaysBaryons = +1, antibaryons = −1, others = 0
Lepton number (L)AlwaysEach generation conserved separately
Strangeness (S)Strong & EM onlyCan change by ±1 in weak interactions

Exchange Particles (Gauge Bosons)

Forces between particles are mediated by the exchange of virtual gauge bosons.

ForceExchange particleActs on
ElectromagneticVirtual photon (γ)Charged particles
Strong nuclearGluon (g)Quarks and gluons
Weak nuclearW+, W, Z0All particles
GravityGraviton (hypothetical)All particles with mass

Beta Decay and the Weak Interaction

β decay: A neutron decays into a proton, emitting an electron and an electron antineutrino. Mediated by a W boson.

n → p + e + ν̄e

At quark level: d → u + e + ν̄e   (via W)

β+ decay: A proton decays into a neutron, emitting a positron and an electron neutrino. Mediated by a W+ boson.

p → n + e+ + νe

At quark level: u → d + e+ + νe   (via W+)

Worked Example

Verify that charge, baryon number and lepton number are conserved in β decay: n → p + e + ν̄e

Charge: 0 → +1 + (−1) + 0 = 0. Conserved.

Baryon number: +1 → +1 + 0 + 0 = +1. Conserved.

Lepton number: 0 → 0 + 1 + (−1) = 0. Conserved.

Exam Tip

The W boson determines which type of weak decay occurs. W carries away negative charge, W+ carries away positive charge. The Z0 mediates interactions where no charge is transferred (e.g., neutrino scattering).

Photoelectric Effect

Key Observations

When electromagnetic radiation is incident on a metal surface, electrons may be emitted. This is the photoelectric effect.

  • Emission occurs only above a certain threshold frequency (f0), regardless of intensity
  • Increasing intensity increases the number of electrons emitted, not their maximum kinetic energy
  • Emission is instantaneous (no time delay)
  • Maximum kinetic energy of photoelectrons depends on frequency, not intensity

These observations cannot be explained by the wave model of light. They require the photon model.

Einstein's Photoelectric Equation

Ek(max) = hf − φ

Where:

  • hf = energy of the incident photon
  • φ (phi) = work function of the metal (minimum energy needed to release an electron)
  • Ek(max) = maximum kinetic energy of the emitted photoelectron

At the threshold frequency: hf0 = φ, so f0 = φ/h

Worked Example

The work function of sodium is 3.65 × 10−19 J. UV light of frequency 8.0 × 1014 Hz is incident on its surface. Calculate the maximum kinetic energy of the emitted electrons.

Ek(max) = hf − φ

= (6.63 × 10−34 × 8.0 × 1014) − 3.65 × 10−19

= 5.30 × 10−19 − 3.65 × 10−19

= 1.65 × 10−19 J

Exam Tip

A common exam question is to plot a graph of Ek(max) vs frequency. The gradient = h (Planck's constant), the y-intercept = −φ, and the x-intercept = threshold frequency f0.

Energy Levels & Line Spectra

Discrete Energy Levels

Electrons in atoms can only exist at specific, discrete energy levels. The lowest energy level is the ground state (n = 1).

When an electron moves between energy levels, it must absorb or emit a photon with energy exactly equal to the difference between the two levels.

ΔE = E2 − E1 = hf = hcλ

Emission and Absorption Spectra

Emission spectrum: When excited atoms de-excite, they emit photons at specific frequencies, producing bright lines on a dark background.

Absorption spectrum: When white light passes through a cool gas, atoms absorb photons at specific frequencies, producing dark lines on a continuous spectrum.

The emission and absorption lines for a given element occur at the same frequencies, as they correspond to the same energy level transitions.

Electron Volt

The electron volt (eV) is a unit of energy commonly used in particle physics.

1 eV = 1.60 × 10−19 J

Worked Example

The ground state of hydrogen is −13.6 eV and the first excited state is −3.4 eV. Calculate the wavelength of the photon emitted when an electron drops from the first excited state to the ground state.

ΔE = −3.4 − (−13.6) = 10.2 eV = 10.2 × 1.60 × 10−19 = 1.63 × 10−18 J

λ = hc / ΔE = (6.63 × 10−34 × 3.00 × 108) / 1.63 × 10−18

λ = 1.22 × 10−7 m = 122 nm (ultraviolet)

Key Facts

  • Energy levels are negative because energy must be supplied to remove the electron (ionise the atom)
  • The ionisation energy corresponds to raising the electron from the ground state to E = 0
  • Line spectra provide evidence for discrete energy levels in atoms

Particles & Radiation Flashcards

Click to flip. Use arrow keys to navigate, space to flip.

Particles & Radiation Quiz

Test your knowledge of particles and radiation.

Particles & Radiation - Mock Exam Questions

Practice exam-style questions. Write your answer, then check the mark scheme.