Atomic Structure
Constituents of the Atom
An atom consists of a small, dense, positively charged nucleus containing protons and neutrons, surrounded by orbiting electrons.
| Particle | Relative charge | Relative mass | Actual mass (kg) |
|---|---|---|---|
| Proton | +1 | 1 | 1.67 × 10−27 |
| Neutron | 0 | 1 | 1.67 × 10−27 |
| Electron | −1 | 1/1836 | 9.11 × 10−31 |
Specific Charge
The specific charge of a particle is its charge divided by its mass. It is measured in C kg−1.
Worked Example
Calculate the specific charge of a proton.
Charge = 1.60 × 10−19 C
Mass = 1.67 × 10−27 kg
Specific charge = 1.60 × 10−19 / 1.67 × 10−27 = 9.58 × 107 C kg−1
Notation and Isotopes
Nuclide notation: AZX, where A = mass number (protons + neutrons), Z = atomic (proton) number.
Isotopes are atoms with the same number of protons but different numbers of neutrons. They have the same chemical properties but different physical properties (e.g., different mass, some may be radioactive).
Key Facts
- The strong nuclear force holds the nucleus together against electrostatic repulsion
- Unstable nuclei can decay by alpha, beta, or gamma emission
- The specific charge of an electron is about 1840 times that of a proton
Particles & Antiparticles
Antimatter
Every particle has a corresponding antiparticle with the same mass but opposite charge (and opposite quantum numbers).
| Particle | Symbol | Antiparticle | Symbol |
|---|---|---|---|
| Electron | e− | Positron | e+ |
| Proton | p | Antiproton | p̄ |
| Neutron | n | Antineutron | n̄ |
| Neutrino | νe | Antineutrino | ν̄e |
Pair Production and Annihilation
Pair production: A photon with sufficient energy creates a particle-antiparticle pair. The minimum photon energy required is 2m0c2 (twice the rest energy of the particle).
Annihilation: A particle meets its antiparticle and they are destroyed, producing two photons travelling in opposite directions (to conserve momentum).
Annihilation: e− + e+ → 2γ
The Photon Model
Electromagnetic radiation is emitted in discrete packets of energy called photons.
Where h = 6.63 × 10−34 J s (Planck's constant), f = frequency, λ = wavelength, c = 3.00 × 108 m s−1.
Exam Tip
In annihilation, two photons are produced (not one) to conserve momentum. Each photon has energy equal to the rest energy of one of the particles (minimum).
Quarks & Leptons
Particle Classification
Particles are classified into two main groups based on whether they feel the strong nuclear force.
Quarks
Quarks are fundamental particles that make up hadrons. There are six flavours, but at A-level you need to know three: up (u), down (d), and strange (s).
| Quark | Symbol | Charge | Baryon number | Strangeness |
|---|---|---|---|---|
| Up | u | +2/3 | +1/3 | 0 |
| Down | d | −1/3 | +1/3 | 0 |
| Strange | s | −1/3 | +1/3 | −1 |
Antiquarks have opposite charge, baryon number, and strangeness.
Quark Composition of Hadrons
| Particle | Quark composition | Charge | Baryon number |
|---|---|---|---|
| Proton | uud | +2/3 +2/3 −1/3 = +1 | +1 |
| Neutron | udd | +2/3 −1/3 −1/3 = 0 | +1 |
| π+ | ud̄ | +2/3 +1/3 = +1 | 0 |
| π− | ūd | −2/3 −1/3 = −1 | 0 |
| K+ | us̄ | +2/3 +1/3 = +1 | 0 |
Leptons
Leptons are fundamental particles that do not feel the strong nuclear force. They include electrons, muons, taus, and their associated neutrinos.
Each lepton generation has its own lepton number: electron lepton number (Le), muon lepton number (Lμ), tau lepton number (Lτ).
Key Facts
- Baryons = 3 quarks, Antibaryons = 3 antiquarks, Mesons = quark + antiquark
- Quarks never exist in isolation (confinement)
- The proton is the only stable baryon; free neutrons decay with a half-life of about 10 minutes
Particle Interactions
Conservation Laws
In all particle interactions, the following quantities must be conserved:
| Quantity | Always conserved? | Notes |
|---|---|---|
| Charge (Q) | Always | Must balance on both sides |
| Baryon number (B) | Always | Baryons = +1, antibaryons = −1, others = 0 |
| Lepton number (L) | Always | Each generation conserved separately |
| Strangeness (S) | Strong & EM only | Can change by ±1 in weak interactions |
Exchange Particles (Gauge Bosons)
Forces between particles are mediated by the exchange of virtual gauge bosons.
| Force | Exchange particle | Acts on |
|---|---|---|
| Electromagnetic | Virtual photon (γ) | Charged particles |
| Strong nuclear | Gluon (g) | Quarks and gluons |
| Weak nuclear | W+, W−, Z0 | All particles |
| Gravity | Graviton (hypothetical) | All particles with mass |
Beta Decay and the Weak Interaction
β− decay: A neutron decays into a proton, emitting an electron and an electron antineutrino. Mediated by a W− boson.
At quark level: d → u + e− + ν̄e (via W−)
β+ decay: A proton decays into a neutron, emitting a positron and an electron neutrino. Mediated by a W+ boson.
At quark level: u → d + e+ + νe (via W+)
Worked Example
Verify that charge, baryon number and lepton number are conserved in β− decay: n → p + e− + ν̄e
Charge: 0 → +1 + (−1) + 0 = 0. Conserved.
Baryon number: +1 → +1 + 0 + 0 = +1. Conserved.
Lepton number: 0 → 0 + 1 + (−1) = 0. Conserved.
Exam Tip
The W boson determines which type of weak decay occurs. W− carries away negative charge, W+ carries away positive charge. The Z0 mediates interactions where no charge is transferred (e.g., neutrino scattering).
Photoelectric Effect
Key Observations
When electromagnetic radiation is incident on a metal surface, electrons may be emitted. This is the photoelectric effect.
- Emission occurs only above a certain threshold frequency (f0), regardless of intensity
- Increasing intensity increases the number of electrons emitted, not their maximum kinetic energy
- Emission is instantaneous (no time delay)
- Maximum kinetic energy of photoelectrons depends on frequency, not intensity
These observations cannot be explained by the wave model of light. They require the photon model.
Einstein's Photoelectric Equation
Where:
- hf = energy of the incident photon
- φ (phi) = work function of the metal (minimum energy needed to release an electron)
- Ek(max) = maximum kinetic energy of the emitted photoelectron
At the threshold frequency: hf0 = φ, so f0 = φ/h
Worked Example
The work function of sodium is 3.65 × 10−19 J. UV light of frequency 8.0 × 1014 Hz is incident on its surface. Calculate the maximum kinetic energy of the emitted electrons.
Ek(max) = hf − φ
= (6.63 × 10−34 × 8.0 × 1014) − 3.65 × 10−19
= 5.30 × 10−19 − 3.65 × 10−19
= 1.65 × 10−19 J
Exam Tip
A common exam question is to plot a graph of Ek(max) vs frequency. The gradient = h (Planck's constant), the y-intercept = −φ, and the x-intercept = threshold frequency f0.
Energy Levels & Line Spectra
Discrete Energy Levels
Electrons in atoms can only exist at specific, discrete energy levels. The lowest energy level is the ground state (n = 1).
When an electron moves between energy levels, it must absorb or emit a photon with energy exactly equal to the difference between the two levels.
Emission and Absorption Spectra
Emission spectrum: When excited atoms de-excite, they emit photons at specific frequencies, producing bright lines on a dark background.
Absorption spectrum: When white light passes through a cool gas, atoms absorb photons at specific frequencies, producing dark lines on a continuous spectrum.
The emission and absorption lines for a given element occur at the same frequencies, as they correspond to the same energy level transitions.
Electron Volt
The electron volt (eV) is a unit of energy commonly used in particle physics.
Worked Example
The ground state of hydrogen is −13.6 eV and the first excited state is −3.4 eV. Calculate the wavelength of the photon emitted when an electron drops from the first excited state to the ground state.
ΔE = −3.4 − (−13.6) = 10.2 eV = 10.2 × 1.60 × 10−19 = 1.63 × 10−18 J
λ = hc / ΔE = (6.63 × 10−34 × 3.00 × 108) / 1.63 × 10−18
λ = 1.22 × 10−7 m = 122 nm (ultraviolet)
Key Facts
- Energy levels are negative because energy must be supplied to remove the electron (ionise the atom)
- The ionisation energy corresponds to raising the electron from the ground state to E = 0
- Line spectra provide evidence for discrete energy levels in atoms
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